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The former is a steam cracker C4 cut rich in n-butylenes (70-80%) after the removal of I,3-butadiene (by hydrogenation) and isobutylene (by hydration to yield MTBE) Raffinate III, in tum, is what remains after the removal of I-butene from raffinate II The Huels process is run below 100 C under sufficient pressure to ensure liquid-phase operation Until the mid-I970s metal-catalyzed propylene dimerization had practical significance in isoprene manufacture Goodyear developed a process to dimerize propylene in the presence of tri-n-propylaluminum to yield 2-methyl-I-pentene 16 ,95,96 This was then isomerized to 2-methyl-2-pentene followed by cracking into isoprene and methane This and other synthetic pocesses, however, are no longer practiced since they are not competitive with isoprene manufactured by cracking of naphtha or gas oil Codimerization of ethylene and I,3-butadiene is also of commercial significance since the product I,4-hexadiene is used as a comonomer in the manufacture of ethylene-propylene-diene elastomers.

The hydrogenation of benzene and its alkyl-substituted derivatives takes place stepwise (Scheme 11.5). On the basis of instrumental and isotope exchange studies, the involvement of rc-adsorbed (8, 9) and cr-adsorbed (10) species was suggested: 96-98

Rhodium and nickel catalysts are used since they are the most active and selective, bringing about the formation of the required trans isomer97 Oligomerization of ethylene to cx-olefins is undeniably the most important oligomerization reaction 17 ,98-101 C IO-C 18 cx-olefins thus produced are used mainly as intermediates to manufacture detergents Three technologies have been commercialized Two processes (Ethyl and Chevron/Gulf) use triethylaluminum to effect Ziegler chain growth chemistry 102 In the conventional ethyl process a stoichiometric chain growth reaction leads to the formation of an aluminum alkyl mixture The chain length of the alkyl groups corresponds to a statistical distribution with a maximum around C6-C IO alkenes The product is usually recycled to get a better yield of the most desirable C6-C 14 alkenes The ethyl technology is a two-step process since the aluminum alkyl mixture is subsequently reacted in a displacement reaction.

Significant activity in telemedicine in Australia began in about 1991 and, as elsewhere, was mostly bottom-up, in this case spearheaded by healthcare organisations and companies at state level. In 1993, Crowe [220] published one of the first articles to raise more general issues and draw attention to the inevitable reimbursement and legal problems that present themselves wherever telemedicine captures attention. John Mitchell of John Mitchell & Associates (Section 2.2.2 and references [4. 61) appears on the scene about this time. His consultancy company was involved in several high-profile projects and Mitchell s evaluation reports on these projects endeavour to extract general principles and make recommendations for further developments (see, for example, the two surveys on South Australian projects to pilot telepsychiatry [221] and renal dialysis [222] that appeared in 1994 and 1995, respectively).

The Language area begins with a pop-up menu that lets you choose a language. You choose a language when you want to replace the existing one, or add new, hyphenation and spelling dictionaries for that language. You can therefore control the dictionaries used by each language separately. For example, if you want to replace the French dictionaries, choose French in the pop-up menu and then select the new French dictionaries elsewhere in this pane. The current dictionaries for the selected language appear in the window beneath it, and there are four buttons (from left to right) to link, add, delete, or save dictionary files.

During this treatment added excess ethylene displaces the alkyl groups to form terminal alkenes and triethylaluminum The first step is carried out at relatively low temperature (90-120 C, 100-200 atm) where chain growth predominates, whereas displacement requires more severe reaction conditions (260-31O C, 7-20 atm) Instead of the displacement reaction, aluminum alkyls may be oxidized with dry air to produce aluminum alkoxides that, after hydrolysis with dilute sulfuric acid or water, yield linear primary alcohols with an even number of carbon atoms (fatty.